Tips and tricks - mdeguzis/SteamOS-Tools GitHub Wiki
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About
This wiki page details various "tips and tricks" around SteamOS and SteamOS-Tools.
Booting directly into Kodi or a certain application
You achieve what this by replacing the last line of /usr/bin/steamos-session with:
steam -tenfoot -steamos -enableremotecontrol steam://rungameid/11312753474682224640
You can obtain this application ID of a non-Steam game by typically running the application, then checking the output out `/tmp/dumps/steam_stdout.txt'