NAC - Open-Quantum-Platform/openqp GitHub Wiki

[NAC]: Non-Adiabatic Coupling (NAC) Options

[NAC] Defaults
Keyword Default Description
type numerical Method for NAC calculation.
dt 1 Time step for NAC calculation.
dx 0.0001 Step size for coordinate displacement.
bp False (No description provided)
nproc 1 Number of processors to use.
restart False Option to restart NAC calculation.
clean False Option to clean up intermediate files.
states 1 2 Specifies the states between which NAC is computed.
alignreorder (none) Option to reorder molecular orbitals (MO) and X components.
[NAC] Details The **nac** section handles Non-Adiabatic Coupling (NAC) calculations.
  • dt: Set the distortion time in atomic units (1 au = 0.02418884254 fs) for runtype=NACME.
    • Details: If dt=1, the NACME value is just the state overlap difference, which can be divided either by time or geometric distortion.
    • Note: Computes all combinations of states of nstate from \[tdhf\]. runtype=NACME requires a previous point as a JSON file provided by the FILE2 keyword.
  • dx: Set the distortion for runtype=NAC (in Bohr).
  • states: Specifies the combination of states for each NAC calculation.

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